4.3 Wineries/Breweries - Fermentation

4.3.1 Emissions

Introduction

This category accounts for the ethanol emissions resulting from the fermentation of grapes at winery located in the Bay Area. During the fermentation process, sugar in the grape juice reacts with yeast to form ethanol (alcohol) and carbon dioxide (CO2) gas. Ethanol is emitted into the atmosphere through evaporation. The amount of ethanol formation is dependent on tank design, length of fermentation period, fermentation temperature, and volume and sugar content of fermenting juice. Sugar content is measured as degrees Brix (grams sugar/100 ml. juice).

Methodology

Wine production in the Bay Area was estimated based on ARB’s methodology and Wine Institute‘s Grape Crush report. Ethanol emission factors from the two types of wine (White and Red) were derived by the ARB from a computer model developed by Williams and Boulton. The ethanol emission factors per thousand gallons of wine produced for white wine, rose wine, and red wine are listed below:

  • White wine: 2.5 lbs.
  • Rose and Red wine: 6.2 lbs.

Using an estimated production of wine as: 41.5% white and 58.5% red wine, a composite emission factor of 4.7 lbs. per thousand gallon of wine produced was derived.

The carbon dioxide (CO2) emission factor was derived from the chemical equation.

\[ C_{6}H_{12}O_{6} + \text{yeast} \rightarrow 2\ C_{2}H_{5}OH + 2\ CO_{2} \]

Assume that fifty percent of CO2 emissions escaped to atmosphere during fermentation process, the CO2 emission factor of 157.41 lbs. per thousands of gallons of wine was estimated. District’s Regulation 3, adopted on May 21, 2008, defined the carbon dioxide (CO2) emissions from wine fermentation processes was biogenic carbon dioxide emissions.

The total emissions for this category are determined by multiplying the emission factor and the wine production. This methodology is presently based on ARB’s methodology (Section 5.1).

Emissions from point sources are calculated from operating data (throughput, emission factors, control factors, if any, etc.) submitted for each equipment as part of the permit process. This operating data is updated upon renewal of the permit.

Monthly Variation

The ethanol emissions associated with wine fermentation occurs during the grape crushing season, which generally runs from mid-August through October.

County Distribution

County distribution was based on the amount of wine production in each county. Alameda, Contra Costa, Napa, Santa Clara, Solano, and Sonoma Counties were assumed to produce wine.

Table 4.5: County fractions.
category ALA CC MAR NAP SF SM SNC SOL SON
#31 Wineries/Breweries, Fermentation 4.2% 0.0% 0.1% 68.1% 0.0% 0.1% 4.3% 0.2% 23.0%
#1904 Wineries/Breweries, Fermentation 4.2% 0.0% 0.1% 68.1% 0.0% 0.1% 4.3% 0.2% 23.0%